Charge Separation Related to Photocatalytic H2 Production from a Ru–Apoflavodoxin–Ni Biohybrid
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چکیده
منابع مشابه
Photocatalytic H2 production from water with rhenium and cobalt complexes.
Photocatalytic hydrogen production in pure water for three component systems using a series of rhenium-based photosensitizers (PS) and cobalt-based water reduction catalysts (WRC), with triethanolamine (TEOA) as an irreversible electron donor, is described. Besides the feasibility of this reaction in water, key findings are reductive quenching of the excited state of the PS by TEOA (k(q) = 5-8 ...
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متن کاملRu–protein–Co biohybrids designed for solar hydrogen production: understanding electron transfer pathways related to photocatalytic function† †Electronic supplementary information (ESI) available: Time traces of photocatalysis, additional EPR spectra and parameters, UV-visible spectroscopy data, and kinetic fits of TA traces. See DOI: 10.1039/c6sc03121h Click here for additional data file.
A series of Ru–protein–Co biohybrids have been prepared using the electron transfer proteins ferredoxin (Fd) and flavodoxin (Fld) as scaffolds for photocatalytic hydrogen production. The light-generated charge separation within these hybrids has been monitored by transient optical and electron paramagnetic resonance spectroscopies. Two distinct electron transfer pathways are observed. The Ru–Fd...
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A series of Ru-protein-Co biohybrids have been prepared using the electron transfer proteins ferredoxin (Fd) and flavodoxin (Fld) as scaffolds for photocatalytic hydrogen production. The light-generated charge separation within these hybrids has been monitored by transient optical and electron paramagnetic resonance spectroscopies. Two distinct electron transfer pathways are observed. The Ru-Fd...
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ژورنال
عنوان ژورنال: ACS Energy Letters
سال: 2016
ISSN: 2380-8195,2380-8195
DOI: 10.1021/acsenergylett.6b00614